Shaw, .C. Frank Person

selected publications

• article

  • Formation and characterization of aurothioneins: Au,Zn,Cd-thionein, Au,Cd-thionein, and (thiomalato-Au)x-thionein..  Biochemistry.  24:1977-1986. 9,
  • Biphasic kinetics of aurothionein formation from gold sodium thiomalate: a novel metallochromic technique to probe Zn2+ and Cd2+ displacement from metallothionein..  Inorganic Chemistry.  29:403-408. 7,
  • Reaction of Cd-7-metallothionein with Cis-Dichlorodiamine Platinum(II)..  Journal of Biological Chemistry.  269:24792-24797. 7,
  • On the rapid, monophasic reaction of the rabbit liver metallothionein a-domain with 5,5'-dithiobis(2-nitrobenzoic acid) (DTNB)..  Inorganic Chemistry.  30:581-583. 6,
  • Reactions of trimethylphosphine analogues of auranofin with bovine serum albumin..  Inorganic Chemistry.  27:3588-3592. 5,
  • Biphasic Reactions of DTNB with Lobster Cdsub 6- and Cdsub 5 Cu-Metallotheionein-2 Which Have Two Type-B (Msub 3 Ssub 9) Clusters..  Inorganic Chemistry.  31:1662-1666. 29,
  • Reactions of auranofin and Et3PAuCl with bovine serum albumin..  Inorganic Chemistry.  25:333-339. 29,
  • Oxidation of the phosphine from the auranofin analogue, triisopropylphosphine(2,3,4,6-tetra-O-acetyl-1-thio-b-D-glucopyranosato-S)gold(I), via a protein-bound phosphonium intermediate..  Journal of the American Chemical Society.  116:2254-2260. 23,
  • Solid-state structure and solution equilibria of cyano(triethylphosphine)gold(I)..  Inorganic Chemistry.  25:3953-3957. 22,
  • Structural consequences of metallothionein dimerization: Solution structure of the isolated Cd-4-alpha-domain and comparison with the holoprotein dimer..  Biochemistry.  42:8403-8410. 22,
  • Exchange reactions between albumin-Au(I)-PEt3 complex and Me3PAuCl or iPr(3)PAuCl: P-31 NMR spectroscopic studies..  Inorganic Chemistry.  5:109-116. 2004
  • Interprotein metal exchange between transcription factor IIIa and apometallothionein..  Journal of Inorganic Biochemistry.  98:639-648. 2004
  • Structure of the Cd-113(3)beta domains from Homarus americanus metallothionein-1: hydrogen bonding and solvent accessibility of sulfur atoms..  Journal of Biological Inorganic Chemistry.  7:713-724. 2002
  • Cadmium and lead interactions with transcription factorIIIA from Xenopus laevis: a model for zinc finger protein reactions with toxic ions and metallothionein..  Marine Environmental Research.  50:89-92. 2000
  • The requirements for stable metallothionein clusters examined using synthetic lobster domains..  Marine Environmental Research.  50:93-97. 2000
  • Sequential proton resonance assignments and metal cluster topology of lobster metallothionein-1..  Biochemistry.  33:8858-8865. 2,
  • {sup}31P NMR Studies of the Formation of a (Cysteine-34)(mu-thiolato) bis(gold(I) triethylphosphine) Species of Bovine Serum Albumin and a Related Model Titration..  Inorganic Chemistry.  31:3706-3710. 2,
  • Interprotein metal ion exchange between cadmium-carbonic anhydrase and apo- or zinc-metallothionein..  Journal of Biological Inorganic Chemistry.  4:784-790. 1999
  • Equilibrium binding constants and facile dissociation of novel serum albumin-dicyanoaurate(I) complexes..  Journal of Biological Inorganic Chemistry.  3:9-17. 1998
  • Kinetics of reversible N-ethylmaleimide alkylation of metallothionein and the subsequent metal release..  Journal of Biological Inorganic Chemistry.  2:65-73. 1997
  • The oxidation of rabbit liver metallothionein-II by 5,5'-dithoiobis(2-nitrobenzoic acid) and glutathione disulfide..  Journal of Inorganic Biochemistry.  52:235-249. 1993
  • sdd Science Bag {sup}TM at the University of Wisconsin-Milwaukee: A successful forum for science outreach..  American Journal of Physics.  61:326. 1993
  • The University of Wisconsin--Milwaukee Science Bag: A Successful Forum for Science Outreach..  Journal of Chemical Education.  69:1020-1023. 1992
  • A magnetic two-dimensional analogue of VSEPR..  Journal of Chemical Education.  68:861. 1991
  • GC-MS and 17O NMR tracer studies of Et3PO formation from auranofin and H217O in the presence of bovine serum albumin: an in vitro model for auranofin metabolism..  Inorganic Chemistry.  27:3406-3409. 1988
  • Presence of Zn,Cu-binding protein in liver of freshwater fishes in the absense of elevated exogenous metal: Relevance to toxic metal exposure..  Marine Environmental Research.  24:147-150. 1988
  • Properties of structure and function of cadmium-binding proteins/peptides form Euglena gracilis..  Marine Environmental Research.  24:159-162. 1988
  • A widespread error in the d6 Tanabe-Sugano diagram..  Journal of Chemical Education.  64:918. 1987
  • Thiol competition for Et3PAuS-albumin: a nonenzymatic mechanism for Et3PO formation..  Journal of Inorganic Biochemistry.  30:177-187. 1987
  • Anti-tumor activity of two binuclear gold(I) complexes with bridging dithiolate ligands..  Inorganica Chimica Acta.  123:213-216. 1986
  • Aurothionein formation from Zn, Cd-thionein and Et3PAuCl, but not Et3PAuSATg(auranofin)..  Inorganica Chimica Acta.  123:197-199. 1986
  • Characterization of protein-bound gold in rat urine following aurothiomalate administration and of rat and human albumin-gold-thiomalate..  Journal of Inorganic Biochemistry.  26:185-195. 1986
  • Role of zinc in the proliferation of euglena gracilis..  Marine Environmental Research.  14:479. 1984
  • C nmr studies of aurothioglucose: Ligand exchange and redox disproportionation reactions..  Journal of Inorganic Biochemistry.  14:267-274. 1981
  • Subcellular distribution of gold in rat renal cortex cells: Limitations of electron microscopy and subcellular fractionation techniques..  Toxicology and Applied Pharmacology.  61:349-357. 1981
  • Bix(L-cysteinato)gold(I): Chemical characterization and identification in renal cortical cytoplasma..  Journal of Inorganic Biochemistry.  10:317-330. 1979
  • Characterization of gold in the cytosol of rat-kidney cortex cells..  Bioinorganic Chemistry.  9:375-388. 1978
  • Complex bis(tertiaryphosphine)dimethylgold(III) cations: phosphine exchange and reductive elimination of ethane..  Journal of Organometallic Chemistry.  51:365-374. 1973
  • PMR spectra of hexamethyl derivatives of group IV-M elements (CH3)3MM'(CH3)3..  Journal of Organometallic Chemistry.  28:53-57. 1971
  • Kinetics and Mechanism of the reaction between serum albumin and auranofin(and its isopropyl analogue) in vitro..  Inorganic Chemistry.  35:424-433. 17,
  • Electrostatic influences on the kinetics of the reactions of lobster metallothioneins with the electrophilic disulfides 2,2'-dithiodipyridine(PYSSPY) and 5,5'-Dithiobis(2-nitrobenzoic acid) (ESSE)..  Inorganic Chemistry.  34:4477-4483. 16,
  • Characterization of Calf Liver Cu,Zn-metallothionein-naturally variable Cu and Zn Stoichiometries..  Biochemical Journal.  317:389-394. 15,
  • Inhibition of Erythrocyte selenium-glutathione peroxidase by auranofin analogues and metabolites..  Biochemical Pharmacology.  55:1291-1299. 15,
  • Properties of the reaction of cis-dichlorodiammineplatinum(II) with metallothionein..  The Journal of Biological Chemistry.  267:16121. 15,
  • Stoichiometry and cluster specificity of copper binding to metallothionein - homogeneous metal clusters..  Biochemical Journal.  317:395-402. 15,
  • Synthesis and characterization of complexes of trialkylphosphine and triarylphosphine gold(I) with thiolated purines and pyrimidines - A class of bifunctional compounds with potential antitumor activity..  Inorganica Chimica Acta..  209:129-135. 15,
  • Thematic issue on metallothioneins - Preface..  Journal of Inorganic Biochemistry.  88:urnal of I. 15,
  • Ligand-scrambling reactions of cyano(trialkyl/triarylphosphine) gold(I) complexes: examination of factors influencing the equilibrium constant..  Inorganic Chemistry.  29:4683-4687. 14,
  • Bovine serum albumin-gold thiomalate complex: 197Au Mossbauer, EXAFS and XANES, electrophoresis, 35S-radiotracer, and fluorescent prob competition studies..  Journal of American Chemical Society.  106:3511-3521. 13,
  • Bovine serum albumin-gold thiomalate complex: 197Au Mossbauer, EXAFS and XANES, electrophoresis, 35S-radiotracer, and fluorescent probe competition studies..  Journal of American Chemical Society.  106:3511-3521. 13,
  • Au-197 Mossbauer characterization of the noncovalent adducts formed between serum albumin and dicyanoaurate(I), a gold-drung metabolite..  Inorganic Chemistry.  38:3268-3269. 12,
  • Reaction of CD-111(7)-Metallothionein with EDTA-a Reappraisal..  Journal of Biological Chemistry.  27:5339-5345. 10,
  • Basal Metallothionein in Tumors: Widespread Presence of Apoprotein..  Journal of Inorganic Biochemistry.  54:91-105. 1,
  • Competition of thiols and cyanide for gold(I)..  Inorganic Chemistry.  25:58-62. 1,
  • The reactions of hemopexin and liver fatty acid-binding protein (L-FABP) with aurothiomalate..  Inorganica Chimica Acta.  153:57-60.

• book

  • Metallothioneins: proceedings of the Pacifichem 2000 Metallothionein Symposium, Honolulu, 14-19 December 2000..  New York: Elsevier. 2002
  • Metallothionein: synthesis, structure, and properties of metallothioneins, phytochelatins, and metal-thiolate complexes..  New York: VCH Publishers. 1992