Publications in VIVO

Co-author Network

Brown, Herbert ISU Faculty Member

Positions

Faculty, Agriculture

Publications
Background
Contact
Other
View All

selected publications

article
- A New Catalytic Enantioselective Reducing Reagent System From Alpha, Alpha, Diphenylpyrrolidinemethanol and 9-Borabicuclo Nonane, Especially Effective for Hindered and Substituted Aralkylketones.. Tetrahedron. 58:1069-1074. 2002
- Selective Reductions. Effective Intramolecular Asymmetric Reductions of Alpha, Beta, and Gamma-Keto Acids With Diisopinocampheylborane and Intermolecular Asymmetric Reductions of the Corresponding Esters With B-Chlorodiisopinocampheylborane.. Journal of Organic Chemistry. 67:5315-5319. 2002
- Asymmetric Synthesis of Goniothalamin, Hexadecanolide, Massoia Lactone, and Parasorbic Acid Via Sequential Allylboration-Esterification, Ring-Closing Metathesis Reactions.. Tetrahedron Letters. 41:583-586. 2000
- First General Synthesis of N-Unsubstituted Imine-Borane Adducts Stable at Room Temperature.. Abstracts of Papers American Chemical Society. 18:641. 1999
- Functions Whose Successive Tangent Lines Enclose Proportional Areas.. The American Mathematical Monthly. 103,:779-787. 1996
- Isopinocampheylchloroborane: A Promising New Reagent for Asymmetric Cyclic Hydroboration. A Simple Procedure to Convert 1-Allyl-1-Cyclohexene into Trans-1 Decalone of Greater or Equal to 99% Optical Purity.. The Journal of Organic Chemistry. 61,:1906-1907. 1996
- Organogoranes for Synthesis. 15 B-Allenly-9-BBN: A Highly Regiospecific and Chemoselective Reagent for Allenlyboration of Representative Carbonyl Compounds, Leading to Homopropargylic Alcohols and Amines.. The Journal of Organic Chemistry. 60,:544-549. 1995
- 2-Isopropylapopinenes. Rates and Stoichiometry of the Hydroboration of Borane-Tetrahydrofuran.. The Journal of Organic Chemistry. 59,:2025-2032. 1994
- Enolboration. 7 Dicyclohexyliodoborane, A Highly Stereoselctive Reagent for the Enolboration for Tertiary Amides. Effects of Solvent and Aldolization Temperature on Stereochemistry in Achieving the Stereoselective Synthesis of Either Syn or Anti Aldols.. The Journal of Organic Chemistry. 59,:7346-7352. 1994
- Hydroboration of Terpenes. 11. Convenient Method for Upgrading 2-Organylapopinenes to High Optical Purity by Reaction of 2-Organylapoisopinocampheylboranes With Suitable Dienes Followed By Displacement with Acetaldehyde.. The Journal of Organic Chemistry. 59,:479-5482. 1994
- Reaction of Aluminum Hydride-Triethylamine Complex With Selected Organic Compounds Containing Representative Functional Goups.. The Journal of Organic Chemistry. 58,:3974-3979. 1993
- Reactions of Sodium Aluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of the Reducing Characteristics of Lithium and Sodium Aluminum Hydrides.. The Journal of Organic Chemistry. 58,:4727-4731. 1993
- Morphological Variation and Age-Class Determination in Overwintering Tadpoles of the Tailed Frog, Ascaphus Truei.. Journal of Zoology. 220,:171-184. 1990
- Developmental Anatomy of the Tailed Frog (Ascaphus Truei): A Primitive Frog With Large Eggs and Slow Development.. Journal of Zoology. 217,:525-537. 1989
- Major Effect of the Leaving Group in Dialkylboron Chlorides and Triflates in Controlling the Stereospecific Conversion of Ketones into Either (E) or (Z) Enol Borinates.. Journal of the American Chemical Society. 111,:3441-3442. 1989
- Vinylic Organoboranes. A Convenient Stereospecific Synthesis of (Z) 1 Halo 1 Alkenes from 1- Alkynes Via (E) 1 Alkenylborane Derivatives with Halogens.. The Journal of Organic Chemistry. 54,:6068-6075. 1989
- Vinylic Organoboranes. A Stereospecific Synthesis of (E) 1 Halo 1 Alkenes from 1 Alkynes.. The Journal of Organic Chemistry. 54,:6075-6079. 1989
- Vinylic Organoboranes. Mercuration of 2-Alkenyl-1, 3, 2-Benzodioxaboroles and Boronic Acids. A Convenient Stereospecific Procedure for the Conversion of Alkynes into 1-Halo-1-Alkenes Via Mercuric Salts.. The Journal of Organic Chemistry. 54,:6079-6084. 1989
- Vinylic Organoboranes. Synthesis of (Z) 1- Halo - 1 Alkenes Via Hydroboration of 1- Halo 1- Alkynes Followed by Protonolysis.. The Journal of Organic Chemistry. 54,:6064-6067. 1989
- 70 Pheromones Via Organoboranes. Vinylic Organoboranes. Stereospecific Synthesis of (Z) and (E) 6 and 7 Alken 1 Ols Via Boracyclenes.. The Journal of Organic Chemistry. 53,:246-250. 1988
- Ring Enlargement Of Boracyclanes Via Sequential One-Carbon Homologation. The First Synthesis of Boracyclanes in the Strained Medium Ring Range.. Journal of the American Chemical Society. 110,:6263-6264. 1988
- Vinylic Organoboranes. A General Stereospecific Synthesis of (Z) and (E) Disubstitutes Alkenes Via Organaboranes.. The Journal of Organic Chemistry. 53,:239-246. 1988
- Vinylic Organoboranes. A Highly Stereospecific and Regiospecific Synthesis of Trisubstituted Alkenes Via Organoboranes.. The Journal of Organic Chemistry. 53,:6009-6013. 1988
- A Highly Diastereoselective Addition of (E) and (Z) Crotyldiisopinocampheylboranes to A Substituted Aldehydes.. The Journal of Organic Chemistry. 52,:3701-3702. 1987
- Addition Compounds of Alkali Metal Hydrides. Preparation of Potassium Dialkoxymonalkylborohydrides From Cyclic Boronic Esters. A New Class of Reducing Agents.. The Journal of Organic Chemistry. 51,:337-342. 1986
- Base Induced A-Alkenylation of Ethyl Bromoacetate, Phenacyl Bromide, and Chloroatonitrile Via B Trans 1 Alkenyl 9 Borabicyclo Nonanes.. The Journal of Organic Chemistry. 51,:3396-3398. 1986
- Chiral Synthesis Via Organoboranes. Hydroboration. Asymmetric Hydroboration of Representative Heterocyclic Olefines With Diisopinocampheylborane. Synthesis of Heterocyclic Boronates and Heterocyclic Alcohols of Very High Enantiomeric Purity.. Journal of the American Chemical Society. 108,:2049-2054. 1986
- Enantiomeric (Z)- and (E)- Crotyldiisopinocampheylbo-Ranes. Synthesis in High Optical Purity of All Four Possible Stereoisomers of B-Methylhomoallyl Alcohols.. Journal of the American Chemical Society. 108,:293-294. 1986
- Highly Efficient Asymmetric Reduction of a Tertiary Alkyl Ketones With Diisopinocampheylchloroborane.. The Journal of Organic Chemistry. 51,:3394-3396. 1986
- Hydroboration. Directive Effects in the Hydroboration of Vinyl and Propenyl Heterocycles With Representative Hydroborating Agents.. The Journal of Organic Chemisty. 51,:439-445. 1986
- Hydroboration. Revision of the Regioselectivity of the Hydroboration of Alkenes With Dihaloborane-Dimethyl Sulfide Complexes.. The Journal of Organic Chemistry. 51,:895-897. 1986
- Hydroboration. Hydroboration of Cyclic Dienes With Representative Hydroborating Agents.. The Journal of Organic Chemistry. 51,:445-449. 1986
- Organoboranes. A Convenient, Highly Efficient Synthesis of Triorganylboranes Via a Modified Organometallic Route.. The Journal of Organic Chemistry. 51,:427-432. 1986
- Pheromones Via Organoboranes. Vinylic Organoboranes. Application of the General Stereoselective Synthesis of (E) Disubstituted Alkenes Via Thexylchloroborane-Dimethyl Sulfide to the Sythesis of Pheromones Containing an (E) Alkene Moiety.. The Journal of Organic Chemistry. 51,:5282-5286. 1986
- Potassium 9-0-9-Boratabicyclo Nonane. A New, Effective Chiral Borohydride Reagent.. The Journal of Organic Chemistry. 51,:1934-1936. 1986
- Vinylic Organoboratnes. Stereoselective Synthesis of (E) 1 Substituted 1 Alkenyl Boronic Esters By the Nucleophilic Substitution of (Z) 1 Bromo 1 Alkenyl Boronic Esters With Organolithium of Grignard Reagents. Isolation and Oxidation to Ketones.. The Journal of Organic Chemistry. 51,:5277-5282. 1986
- A Convenient Method for Upgrading the Enantiomeric Purities of Longifolene and 3 Carene to Materials Approaching 100 EE.. The Journal of Organic Chemistry. 50,:3203-3206. 1985
- Addition Compounds of Alkali Metal Hydrides. A General Method For Preparation of the Potassium 9-Alkoxy-9-Boratabicyclo Nonanes. A New Class of Stereoselective Reducing Agents.. The Journal of Organic Chemistry. 50,:e Journal-553. 1985
- An Asymmetric Synthesis That's Really General.. Chemtech. 15,:572-575. 1985
- Asymmetric Synthesis of the Diastereomeric 1-1-Alkanols in High Optical Purity Via a Stereochemically Stable Allylic Borane, B-2-Cyclohexen-1-Yldiisopinocampheylborane.. Journal of the American Chemical Society. 107,:2564-2565. 1985
- Chiral Synthesis Via Organoboranes. Conversion of Boronic Esters of Essentially 100 Optical Purity To Aldehydes, Acids and Homologated Alcohols of Very High Enantiomeric Purities.. Journal of the American Chemical Society. 107,:4980-4983. 1985
- Chiral Synthesis Via Organoboranes. Rapid Reaction of Boronic Esters of Very High Opitical Purity with Lithium Aluminum Hydride. Facile Reaction of Essentially Optically Pure Borinic Esters with Lithium Monoethoxyaluminohydride. A Novel and Quantitative Synthesis of Lithium Monoalkyl and Dialkylborohydrides of Essentially 100 Optical Purity.. Journal of the American Chemical Society. 107,:460-464. 1985
- Chiral Synthesis Via Organoboranes. Synthetic Utility of Boronic Esters of Essentially 100 Optical Purity. Synthesis of Homologated Boronic Acids and Esters of Very High Enantiomeric Purities.. The Journal of Organic Chemistry. 50,:5583-5586. 1985
- Diisopinocampheylchloroborane, A Remarkable Efficient Chiral Reducing Agent for Aromatic Prochiral Ketones.. The Journal of Organic Chemistry. 50,:5446-5448. 1985
- Hydroboration Kinetics. A Reinvestigation of the Kinetics of Hydroboration of Representative Alkenes with Disiamylborane Dimer. Conclusive Evidence for the Dissociation Mechanism in the Hydroboration of Alkenes with Dialklborane Dimers.. The Journal of Organic Chemistry. 50,:518-520. 1985
- Hydroboration. Hydroboration of Representative Heterocyclic Olefins with Borane-Methyl Sulfide, 9-Borabicyclo Nonane, Dicyclohexylborane, and Disiamylborane. Synthesis of Heterocyclis Alcohols.. The Journal of Organic Chemistry. 50,:1582-1589. 1985
- Hydroboration. Hydroboration-Oxidation of 1, 4-Epoxy -1, 4-Dihydronaphthalene With and Without Ring Opening.. The Journal of Organic Chemistry. 50,:3002-3005. 1985
- Hydroboration. Relative Rates of Hydroboration of Representative Heterocyclic Olefins with 9-Borabicyclo Nonane.. The Journal of Organic Chemistry. 50,:583-5586. 1985
- Organoboranes. A Facile and Highly Efficient Addition of B-1-Alkynyl-9-Borabicyclo Nonanes to Aldehydes and Ketones: An Exceptionally Chemoselective Synthesis of Propargylic Alcohols.. The Journal of Organic Chemistry. 50,:1577-1582. 1985
- Organoboranes. Reaction of Organoboranes With (Dichloromethyl) Lithium. Scope and Limitations. Synthesis of Homologated Primary and Secondary Alcohols.. The Journal of Organic Chemistry. 50,:4032-4036. 1985
- Selective Reductions. Asymmetric Reduction of Prochiral Ketones With B-9-Borabicyclo Nonane.. The Journal of Organic Chemistry. 50,:1384-1394. 1985
- Solvomercuration-Demercuration. The Solvomercuration-Demercuration of Olefins in Alcohol Solvents With Mercuric Trifluroacetate- An Ether Synthesis of Wide Generality.. The Journal of Organic Chemistry. 50,:1171-1174. 1985
- Structural Effects in Solvolytic Reactions. Direct Search for the Nonclassical Stabilization Energy in the Ionization of 2-Norbornyl Derivatives. Consistent Absence of Nonclassical Stabilization in the Ionization of 2-Norbornyl Derivatives in Solvoytic or Superacid Media.. The Journal of Organic Chemistry. 50,:5578-5583. 1985
- Structural Effects in Solvolytic Reactions. Steric Retardation in the Solvolysis of Tertiary Endo Bicyclic Derivatives. Evidence That the Exo:Endo Rate/Product Ratios for Typical Reactions in Rigid U-Shaped Bicyclics is a General Steric Phenomenon.. The Journal of Organic Chemistry. 50,:2179-2188. 1985
- Structural Effects in Solvolytic Reactions. Examination of the Differences in the Behavior of Secondary and Tertiary U-Shaped Bicyclic Derivatives Toward Solvolysis.. The Journal of Organic Chemistry. 50,:5574-5577. 1985
- Structural Effects in Solvolytic Reactions. Rates of Ethanolysis of Camphene Hydrochloride and Related A-Methyl-Substituted 1-Chloro-1-Methylcyclopentanes. Is the Rate of Ethanolysis of Camphene Hydrochloride Exceptionally High?. The Journal of Organic Chemistry. 50,:826-829. 1985
- Structural Effects in Solvolytic Reactions. Steric Effects as a Major Factor in the Exo:End Rate Ratios for the Solvolysis of 2, 7, 7-Trimethyl and 2, 6, 6-Trimethy-2-Norbornyl P-Nitrobenzoates.. The Journal of Organic Chemistry. 50,:1165-1167. 1985
- The Polycyclic Hydroboration of Acyclic and Cyclic Trienes With Borane in Tetrahydrofuran and Triethylamine-Borane. Reexamination of the Stereochemistry of Isometric Perhydro-9B-Boraphenalenes.. The Journal of Organic Chemistry. 50,:520-527. 1985
- A New, Highly Stereoselective Reducing Agent, Potassium 9-9-Boratabicyclo Nonane.. The Journal of Organic Chemistry. 49,:2073-2074. 1984
- Addition Compounds of Alkali-Metal Hydrides. A General Method for Preparation of Potassium Trialkoxyborohydrides. A New Class of Reducing Agents.. Inorganic Chemistry. 23,:2929-2931. 1984
- B-Allyldiisocaranylborane: A New, Remarkable Enantioselective Allylborating Agent for Prochiral Aldehydes. Synthesis of Homoallylic Alcohols Approaching 100 Enantiomeric Purities.. The Journal of Organic Chemistry. 49,:4089-4091. 1984
- Conjugate Addition-Elimination in the Reaction of B-1-Alkenyl-9-Borabicyclo Nonames With 4-Methoxy-3-Buten-2-One. A Convenient New Route to Conjugated Dienones.. The Journal of Organic Chemistry. 49,:5024-5025. 1984
- Exceptionally Facile Reduction of Acyclic and Alicyclic Carboxylic Acids to Aldehydes by Thexylchloroborane-Dimenthlyl Sulfide.. Journal of the American Chemical Society. 106,:8001-8002. 1984
- Hydroboration Kinetics. Kinetics, Mechanism, and Selectivitiy for Hydroboration of Representative Alkenes with Borinane.. Journal of American Chemical Society. 106,:3768-3771. 1984
- Hydroboration. Addition of Lithium Triethlyborohydride to Substituted Styrenes. A Simple, Convenient Procedure for the Markovnikov Hydroboration of Armoatically Conjugated Olefins and the Synthesis of Unusual Mixed Traillylboranes.. The Journal of Organic Chemistry. 49,:1064-1071. 1984
- Hydroboration. Hydroboration Characteristics of Lithium Borohydride/Ethyl Acetate in Ethyl Ether. A New Series for Controlled Hydroboration of Alkenes and Alkynes.. The Journal of Organic Chemistry. 49,:4822-4827. 1984
- Molecular Addition Compounds. Effect of Structure on the Reactivities of Representative Borane-Amine Complexes in Typical Reactions Such As Hydrolysis, Hydroboration, and Reduction.. Inorganic Chemistry. 23,:2746-2753. 1984
- Selective Reductions. Asymmetric Reduction of Representative Keyones With Monoisopinocampheylborane of High Optical Purity.. The Journal of Organic Chemistry. 49,:2558-2560. 1984
- Selective Reductions. Reaction of Lithium 9-Boratabicyclo Nonane With Selected Organic Compounds Containing Representative Functional Groups.. The Journal of Organic Chemistry. 49,:3091-3097. 1984
- Selective Reductions. Reaction of Representative Organic Functional Groups with Lithium Borohydride in the Presence of B-Methoxy-9-Borabicyclo Nonane. A Simple, Convenient Procedure for the Catalyzed Selective Reduction of Esters.. The Journal of Organic Chemistry. 49,:3891-3898. 1984
- Solvomercuration-Demercuration. Alkoxymercuration-Demercuration of Representative Alkenes in Alcohol Solvents With The Mercuric Salts Acetate, Trifluoroacetate, Nitrate, and Methanesulfonate.. The Journal of Organic Chemistry. 49,:2551-2557. 1984
- Structural Effects in Solvolytic Reactions. Effects of P-Alkyl and P-Cycloalkyl Groups on the Carbon-13 NMR Shifts of the Cationic Carbon Center in P-Alkyl-Tert-Cumly Cations.. The Journal of Organic Chemistry. 49,:2754-2757. 1984
- Hydride Reductions: A 40-Year Revolution in Organic Chemistry.. Chemical & Engineering News. 57:24-29. 1979
- Chemical Discovery.. Chemical and Engineering News. 52:34-36. 1974
- Embryonic Temperature Adaptations & Genetic Compatibility in Two Allopatric Populations of the Spadefoot Toad, Scaphiopus Hammondi.. Evolution. 21:742-761. 1967
- New Selective Reducing Agents.. Journal of Chemical Education. 38,:173-179. 1961
- Tips on Transitor Radio Service.. Electric World. 64,:34-35. 1960
- Chemistry of Molecular Shapes.. Journal of Chemical Education. 36,:424-431. 1959
- Foundations of the Structural Theory.. Journal of Chemical Education. 36,:104-110. 1959
- Tape Recording Industry.. Electric World. 62,:67. 1959
book
- Organoboranes for Syntheses.. Washington, DC: American Chemical Society. 2001
- The Nonclassical Ion Problem.. New York: Pienum Press. 1976
- Soybeans Acreage Response to Price and Farm Program Changes.. Washington, DC: Economic Research Service, U.S. Dept. of Agricultu. 1971
- Peanut-Cotton Farms Organization, Costs, and Returns, Southern Coastal Plains, 1944-1960.. Washington, DC: Farm Economics Division, Economic Research Service. 1962
- Cotton Farms, San Joaquin Valley, California Organization, Costs and Returns, 1947-1959.. Washington DC: Farm Economics Division, Economic Research Service. 1961
- Cotton Farms, San Joaquin Valley, California: Organization, Costs, and Returns, 1947-1959.. Washington: Farm Economics Division, Economic Research Service. 1961
- Cotton Farming in the Southern Piedmont, 1930-1951: Organization, Costs, and Returns.. Washington, DC: U.S. Dept. of Agriculture, Bureau of Agricultural. 1952
- Factors Affecting the Yield of Kraut Cabbage in Ohio as Determined By a Survey and Cooperative Field Tests.. Wooster, OH: Ohio Agricultural Experiment Station. 1936
- Organic Syntheses Via Boranes.. New York.
thesis or dissertation
- Colostrum-Acquired Immunity and Active Antibody Production in Baby Pigs. 1959